全文获取类型
收费全文 | 1002篇 |
免费 | 57篇 |
国内免费 | 2篇 |
专业分类
化学 | 685篇 |
晶体学 | 2篇 |
力学 | 53篇 |
数学 | 154篇 |
物理学 | 167篇 |
出版年
2023年 | 9篇 |
2022年 | 14篇 |
2021年 | 50篇 |
2020年 | 40篇 |
2019年 | 28篇 |
2018年 | 28篇 |
2017年 | 20篇 |
2016年 | 71篇 |
2015年 | 40篇 |
2014年 | 42篇 |
2013年 | 69篇 |
2012年 | 83篇 |
2011年 | 112篇 |
2010年 | 53篇 |
2009年 | 34篇 |
2008年 | 51篇 |
2007年 | 57篇 |
2006年 | 54篇 |
2005年 | 55篇 |
2004年 | 30篇 |
2003年 | 34篇 |
2002年 | 23篇 |
2001年 | 5篇 |
2000年 | 11篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 6篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1970年 | 1篇 |
1961年 | 1篇 |
1948年 | 1篇 |
1938年 | 1篇 |
1937年 | 1篇 |
1918年 | 1篇 |
1916年 | 1篇 |
排序方式: 共有1061条查询结果,搜索用时 214 毫秒
61.
Working in the Wannier representation, we derive an expression for the orbital magnetization of a periodic insulator. The magnetization is shown to be comprised of two contributions, an obvious one associated with the internal circulation of bulklike Wannier functions in the interior, and an unexpected one arising from net currents carried by Wannier functions near the surface. Each contribution can be expressed as a bulk property in terms of Bloch functions in a gauge-invariant way. Our expression is verified by comparing numerical tight-binding calculations for finite and periodic samples. 相似文献
62.
Dionigi C Nozar P Di Domenico D Calestani G 《Journal of colloid and interface science》2004,275(2):445-449
In this paper we propose a simple model for the formation of monodisperse polymer colloids, which provides a convenient set of synthetic parameters for given bead diameters. We provide experimental data in support of this model. 相似文献
63.
[reaction: see text] The ring-closing olefin metathesis (RCM) of 2,2'-divinylbiphenyls, using a second-generation RCM ruthenium-based catalyst, leads to differently substituted phenanthrenes in quantitative yield under very mild reaction conditions, independent of both nature and position of the groups present on the biphenyl moiety. 相似文献
64.
We consider an elliptic operator of second order with Dirichlet boundary
conditions in a cylindrical domain. We show that a suitable interpretation of this
operator in a certain space of continuous functions vanishing on the boundary is
the infinitesimal generator of an analytic semigroup in the space of continuous
functions. We prove several inclusions of the domain of the infinitesimal generator
and of the real interpolation spaces between this domain and the basic space of
continuous functions. 相似文献
65.
We show that, in low-dimensional photonic bandgaps, wave diffraction resulting from localization in the translational-invariant directions is strongly influenced by the photonic band structure of the periodic crystal, leading to new kinds of wave localization. In particular, for a periodic layered structure we show that, close to a bandgap edge, diffraction is enhanced, with a transition from a parabolic diffraction curve-typical of isotropic media and supporting Gaussian beams-to hyperbolic or elliptic diffraction curves. In the last two cases localization in the form of stationary X-shaped or sinc-shaped waves is possible. 相似文献
66.
Bianco A Pantarotto D Hoebeke J Briand JP Prato M 《Organic & biomolecular chemistry》2003,1(23):4141-4143
A peptide analogue from a histone H3 protein containing the L-fulleropyrrolidino-glutamic acid has been prepared by a solid-phase approach and has been fully characterized. By molecular modelling it was verified that this peptide derivative is able to retain a binding capacity to the MHC (major histocompatibility complex) molecule similar to that of the cognate epitope. 相似文献
67.
Ricci D Di Valentin C Pacchioni G Sushko PV Shluger AL Giamello E 《Journal of the American Chemical Society》2003,125(3):738-747
On the basis of embedded cluster calculations, we propose a new model for the structure of paramagnetic color centers at the MgO surface usually denoted as F(S)(H)(+) (an electron trapped near an adsorbed proton). These centers are produced by exposing the surface of polycrystalline MgO to H(2) followed by UV irradiation. We demonstrate that properties of H atom absorbed at surface sites such as step edges (MgO(step)) and reverse corner sites (MgO(RC)), formed at the intersection of two step edges, are compatible with a number of features observed for F(S)(H)(+). Our calculations suggest that (i) H(2) dissociates at the reverse corner site heterolytically and that there is no barrier for this exothermic reaction; (ii) the calculated vibrations of the resulting MgO(RC)(H(+))(H(-)) complex are fully consistent with the measured ones; (iii) desorption of a neutral H atom from the diamagnetic precursor requires UV light and leads to the formation of stable neutral paramagnetic centers at the surface, MgO(step)(H(+))(e(-))(trapped) and MgO(RC)(H(+))(e(-))(trapped). The computed isotropic hyperfine coupling constants and optical transitions of these centers are in broad agreement with the existing experimental data. We argue that these centers, which do not belong to the class of "oxygen vacancies", are two of the many possible forms of the F(S)(H)(+) defect center. 相似文献
68.
Davide Franco 《Geometriae Dedicata》2000,81(1-3):33-52
Extending a result of Manivel, we prove the following: THEOREM. Suppose $\sum\limits_i {b_i \geqslant } \sum\limits_i {a_i } + n$ and $$\sum\limits_i {b_i } [n + d_i d_i - 1] \geqslant \sum\limits_i {a_i } [n + l_i l_i - 1] + n.$$ Then the kernel E(d) of the general morphism: $$\mathop \oplus \limits_{i = 1}^v (Bi \otimes O_{P^n } (d_i )) \to \mathop \oplus \limits_{j = 1}^v (A_j \otimes O_{P^n } (l_i ))$$ (l 1>...>l s>d 1>...>d v) is a globally generated vector bundle, except for at most finitely many sets $\left\{ {b_i ,a_i } \right\}$ . 相似文献
69.
70.
Cristina Cimarelli Davide Fratoni Andrea Mazzanti Gianni Palmieri 《Tetrahedron: Asymmetry》2011,22(5):2991-596
A novel synthesis of useful enantiomerically pure arylglycinates via spontaneous reaction between phenol or naphthol derivatives and enantiopure α-imino glyoxylate in the absence of an acid catalyst is reported. A library of enantiopure substituted phenol or naphthol glycinates was obtained in good yields and high diastereoselectivities. Diastereoisomerically pure aryl glycinates were obtained by direct flash chromatography separation of the crude reaction mixture. The free OH moiety of the phenols or naphthols contributed to the activation of the imino group to form an intermolecular hydrogen bond and promoted the reaction in the absence of an acid catalyst, as shown in the transition state reported. The diastereoselectivity is due to thermodynamic control in the addition step. 相似文献